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This article in SSSAJ

  1. Vol. 73 No. 1, p. 72-81
     
    Received: Jan 29, 2008
    Published: Jan, 2009


    * Corresponding author(s): nirichter@yahoo.de
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doi:10.2136/sssaj2008.0025

Free Iron Oxide Determination in Mediterranean Soils using Diffuse Reflectance Spectroscopy

  1. N. Richter *a,
  2. T. Jarmerb,
  3. S. Chabrillata,
  4. C. Oyonartec,
  5. P. Hostertd and
  6. H. Kaufmanna
  1. a Remote Sensing Section, GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam, Germany
    b Transportation and GeoInformation Eng. Unit, Faculty of Civil and Environ. Eng., Technion, Haifa 32000, Israel
    c Dep. of Soil Science, Univ. of Almería, 04120-Almería, Spain
    d Institute of Geography, Geomatics Dep., Humboldt-Universität zu Berlin, 10099 Berlin, Germany

Abstract

Soil Fe oxides occur in almost all soils and reflect different environmental conditions by the high variability of their mineralogy and concentration. Quantitatively determining this important pedogenic indicator enables diffuse reflectance spectroscopy (DRS) based on material-specific absorption characteristics. This paper presents a methodology that directly links free Fe oxide content (Fed, citrate-dithionite extractable Fe) with the diagnostic Fe absorption band near 900 nm (Fe-NIR). In addition, we investigated the influence of soil texture on the spectral characteristics and prediction accuracy. We showed that the Fe absorption bands of clay-dominated soil samples were, in general, deeper than sand-dominated samples with comparable Fed content. Based on the Fe-NIR absorption depth, we created two texture-dependent Fed prediction models, retrieving the best Fed estimates for the sand calibrated model (R 2 v = 0.87, rel. MSEv = 13.9%). Due to the high texture variability in sand, silt, and clay fractions of the clay–silt dominated samples, the clay–silt calibrated model produced good predictions (R 2 v = 0.70, rel. RMSEv = 19.0%). The soil texture appeared to have no significant influence on model stability but did affect the prediction accuracy. Constant Fed contents were over- and underestimated when applying the texture-dependent models to other texture groups. The texture-independent model was stable and performed well (R 2 v = 0.76, rel. RMSEv = 18.1%). These results are highly relevant to the subsequent spatial assessment of free Fe oxide content as an indicator for soil development from hyperspectral remote sensing data.

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